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Rahlf, Peer; Laukert, Georgi; Hathorne, Ed C; Vieira, Lucia Helena; Frank, Martin (2020): Neodymium and hafnium isotopes and rare earth element concentrations from water bottle samples measured during METEOR cruise M121 along the Congo River plume (GEOTRACES cruise GA08) [dataset]. PANGAEA, https://doi.org/10.1594/PANGAEA.925602

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Abstract:
To better understand the inputs of riverine REEs and Hf to the ocean and their impact on the open ocean we collected filtered seawater samples from 16 full water column profiles along the Congo River plume at the coast of Congo and Gabon and along an offshore section at 3°S, complemented by three freshwater samples collected directly from the Congo River. The water samples from the Congo River plume were collected during GEOTRACES cruise GA08 with German RV Meteor (M121) in November and December 2015 with a stainless steel CTD rosette and a towed fish for surface waters. River water end-member samples from the Congo River at zero salinity were taken upstream by boat in May, July and October 2017 near the center of the river at ~6°S and ~12.5°E (stations 12.1–12.3). We determine for the first time REE and Hf concentrations and isotope compositions within the Congo River plume and quantify Nd and Hf fluxes. Based on these data we evaluate how far the Congo River plume is traceable by these geochemical parameters, how it contributes to their budgets in the South East Atlantic Ocean, and to which degree the Nd and Hf isotope and REE distributions can be used as water mass tracers in areas of high continental inputs.
Keyword(s):
Angola Basin; Congo River; hafnium; Neodymium; South East Atlantic Ocean
Supplement to:
Rahlf, Peer; Laukert, Georgi; Hathorne, Ed C; Vieira, Lucia Helena; Frank, Martin (2021): Dissolved neodymium and hafnium isotopes and rare earth elements in the Congo River Plume: Tracing and quantifying continental inputs into the southeast Atlantic. Geochimica et Cosmochimica Acta, 294, 192-214, https://doi.org/10.1016/j.gca.2020.11.017
Coverage:
Median Latitude: -3.794493 * Median Longitude: 7.312899 * South-bound Latitude: -7.280000 * West-bound Longitude: 0.010000 * North-bound Latitude: -3.000000 * East-bound Longitude: 12.490000
Date/Time Start: 2015-11-29T00:00:00 * Date/Time End: 2017-10-08T00:00:00
Minimum DEPTH, water: m * Maximum DEPTH, water: 4485 m
Event(s):
Congo_River_12-1 * Latitude: -6.070000 * Longitude: 12.490000 * Date/Time: 2017-07-22T00:00:00 * Method/Device: Sampling river (RIVER)
Congo_River_12-2 * Latitude: -6.070000 * Longitude: 12.490000 * Date/Time: 2017-10-08T00:00:00 * Method/Device: Sampling river (RIVER)
Congo_River_12-3 * Latitude: -6.070000 * Longitude: 12.490000 * Date/Time: 2017-05-04T00:00:00 * Method/Device: Sampling river (RIVER)
Parameter(s):
#NameShort NameUnitPrincipal InvestigatorMethod/DeviceComment
1Event labelEventFrank, Martin
2Station labelStationFrank, Martin
3DATE/TIMEDate/TimeFrank, MartinGeocode
4LATITUDELatitudeFrank, MartinGeocode
5LONGITUDELongitudeFrank, MartinGeocode
6DEPTH, waterDepth watermFrank, MartinGeocode
7Temperature, waterTemp°CFrank, Martin
8SalinitySalFrank, Martin
9Neodymium-143/Neodymium-144 ratio143Nd/144NdLaukert, Georgi
10ε-Neodymiumε-NdLaukert, Georgi{(143Nd/144Nd)/CHUR − 1} × 10 000, with CHUR = 0.512638
11ε-Neodymium, standard deviationε-Nd std dev±Laukert, Georgi2SD, internal
12ε-Neodymium, standard deviationε-Nd std dev±Laukert, Georgi2SD, external
13Neodymium, dissolvedNd disspmol/kgLaukert, GeorgiIsotope dilution
14Hafnium-176/Hafnium-177176Hf/177HfLaukert, Georgi
15ε-Hafniumε-HfLaukert, Georgi{(176Hf/177Hf)/CHUR − 1} × 10 000, with CHUR = 0.282785
16ε-Hafnium, standard deviationε-Hf std dev±Laukert, Georgi2SD, internal
17ε-Hafnium, standard deviationε-Hf std dev±Laukert, Georgi2SD, external
18Hafnium, dissolvedHf disspmol/kgLaukert, GeorgiIsotope dilution
19Lanthanum, dissolvedLa disspmol/kgLaukert, GeorgiICP-MS, Elemental Scientific, seaFAST2SD = 24.8 %
20Cerium, dissolvedCe disspmol/kgLaukert, GeorgiICP-MS, Elemental Scientific, seaFAST2SD = 18.4 %
21Praseodymium, dissolvedPr disspmol/kgLaukert, GeorgiICP-MS, Elemental Scientific, seaFAST2SD = 18.3 %
22Neodymium, dissolvedNd disspmol/kgLaukert, GeorgiICP-MS, Elemental Scientific, seaFAST2SD = 4.9 %
23Samarium, dissolvedSm disspmol/kgLaukert, GeorgiICP-MS, Elemental Scientific, seaFAST2SD = 10.1 %
24Europium, dissolvedEu disspmol/kgLaukert, GeorgiICP-MS, Elemental Scientific, seaFAST2SD = 9.6 %
25Gadolinium, dissolvedGd disspmol/kgLaukert, GeorgiICP-MS, Elemental Scientific, seaFAST2SD = 18.9 %
26Terbium, dissolvedTb disspmol/kgLaukert, GeorgiICP-MS, Elemental Scientific, seaFAST2SD = 15.2 %
27Dysprosium, dissolvedDy disspmol/kgLaukert, GeorgiICP-MS, Elemental Scientific, seaFAST2SD = 6.3 %
28Holmium, dissolvedHo disspmol/kgLaukert, GeorgiICP-MS, Elemental Scientific, seaFAST2SD = 12.7 %
29Erbium, dissolvedEr disspmol/kgLaukert, GeorgiICP-MS, Elemental Scientific, seaFAST2SD = 9.4 %
30Thulium, dissolvedTm disspmol/kgLaukert, GeorgiICP-MS, Elemental Scientific, seaFAST2SD = 23.3 %
31Ytterbium, dissolvedYb disspmol/kgLaukert, GeorgiICP-MS, Elemental Scientific, seaFAST2SD = 16.7 %
32Lutetium, dissolvedLu disspmol/kgLaukert, GeorgiICP-MS, Elemental Scientific, seaFAST2SD = 14.7 %
Change history:
2021-04-29T09:59:28 – ε-Neodymium: corrected to negative values
Size:
1257 data points

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